Abstract
MO(CO)(6) was reacted with the Schiff base ligand obtained by condensation reaction of 2-acetyl- or benzoylpyridine with poly(propylene glycol)bis(2-aminopropyl ether) to obtain polymeric, dinuclear metal tetracarbonyl compounds. The long-chain Schiff base complexes are highly soluble even in non-polar solvents such as petroleum ether, diethyl ether and n-hexane. These complexes, as free-radical initiators, afforded methyl methacrylate polymerization in chlorinated solvents. Copyright (C) 2004 John Wiley Sons, Ltd.
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Kapsamı
Uluslararası
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Type
Hakemli
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Index info
WOS.SCI
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Language
English
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Article Type
None
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Keywords
metal-polymer complexes heteroatom-containing polymers polyether poly(methyl methacrylate) transition metal chemistry propylene glycol organometallic catalysts